Aircraft front fastening plate VHS-497 (2) - Al Cu Sn Zn Si Alloy - Modern Times

Aircraft front fastening plate VHS-497 (2) - Al Cu Sn Zn Si Alloy - Modern Times

Aircraft front fastening plate VHS-497 (2)

Marianne. Senn (EMPA, Dübendorf, Zurich, Switzerland) & Christian. Degrigny (HE-Arc CR, Neuchâtel, Neuchâtel, Switzerland)

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Credit HE-Arc CR.

Fig. 1: Photograph of the aeroplane showing the location of the fixation plate (red dot) (www.hepta.aero),

Fixation plate for the wooden construction, broken by use (Fig. 1).

Aeroplane part

Dufaux IV aeroplane

Biplane built by Henri and Armand Dufaux in 1909/10

Modern Times

1909 _ 1910

Outdoor to indoor atmosphere

Swiss Museum of Transport, Luzern, Lucerne

Swiss Museum of Transport, Luzern, Lucerne

VHS-497 (2)

Not known

Complementary information

Nothing to report.

Credit HE-Arc CR.

Fig. 2: Location of sampling area,

Stratigraphic representation: none.

Credit HE-Arc CR.

Fig. 3: Micrograph of the cross-section showing the location of Figs. 5 to 9,

The top part has been cut during sampling (Fig. 2). The more regular right side is the plate surface and the irregular side is the broken edge (Fig. 3). Dimensions: L = 4mm ; W = 4mm.

Al Cu Sn Zn Si Alloy

As-cast

DUF-4

Empa (Marianne Senn)

Swiss Museum of Transport, Luzern, Lucerne

September 2007, metallography and alloy composition

Complementary information

Nothing to report.

Analyses performed:
Metallography (unetched), Vickers hardness testing, SEM/EDS.

The metal is an aluminium alloy containing Cu, Sn, Zn and Si (Table 1). The unetched metal shows an as-cast structure consisting of the aluminium matrix with Sn (not soluble in Al) inclusions (Figs. 5 and 6), intermetallic compounds such as Al2Cu (Fig. 5, red arrows) and clusters of Al,Fe,Cu & Si phases (Fig. 5, black arrows). There are porosities in the metal (Figs. 3 and 5). The average hardness of the metal is HV1 80.

Elements

 Al Cu Sn Zn Si Fe O Fe Total
Metal (average) 89 4.6 3 1.6 1 < 0.8 < 100
Intermetallic compounds 45 55 < < < < < < 100
Al,Fe,Si,Cu phase clusters 58 11 < < 7.5 29 3.4 29 109
Sn inclusions < < 100 < < < < < 100

Table 1: Chemical composition (mass %) of the metal and inclusions (from Fig. 5). Method of analysis: SEM/EDS, Laboratory of Analytical Chemistry, Empa.

Credit HE-Arc CR.

Fig. 5: Micrograph of the metal sample from Fig. 3 (detail), unetched, bright field. The cast structure is revealed by light grey intermetallic compounds (Al2Cu, red arrows), dark-grey Al,Fe,Si & Cu phase clusters (black arrows) and Sn inclusions (nodules). On the top left some pores can be seen,

Credit HE-Arc CR.

Fig. 6: SEM image of the metal sample from Fig. 3 (detail), SE-mode, unetched. We observe in dark-grey the metal matrix, in medium-grey the intermetallic compound Al2Cu as well as Al,Fe,Si & Cu phase clusters and in light-grey the Sn inclusions,

Dendritic structure with inclusions

Al

Si, Cu, Zn, Sn

Complementary information

Nothing to report.

No corrosion layer can be seen on the metal surface (Figs. 3 and 7). Under polarized light small white and brown particles are visible on the broken edge (D1, Fig. 8). Their analysis reveals the presence of silica particles surrounded by dirt (Table 2 and Fig. 9). The metal surface is covered by a thin oxygen bearing skin (CP1, Fig. 9).

Elements

 O Al Si Cu Total
Adherent particle (average of 3 similar analyses) 55 0.6 50 1.1 106

Table 2: Chemical composition (mass %) of the adhering particles to the metal surface (from Fig. 7). Method of analysis: SEM/EDS, Laboratory of Analytical Chemistry, Empa.

Credit HE-Arc CR.

Fig. 7: Micrograph showing the metal - “corrosion products” interface from Fig. 3 (reversed picture, detail), unetched, bright field. We observe in white the metal matrix, in dark-grey Al,Fe, Si & Cu phase and light-grey Al2Cu intermetallic compounds. The micrograph of Fig. 8 is marked by a rectangle,

Credit HE-Arc CR.

Fig. 8: Micrograph from Fig. 7 (detail) and corresponding to the stratigraphy of Fig. 4, unetched, polarised light. We observe in grey the metal matrix and blue-brown the adherent material. The micrograph of Fig. 9 is marked by a rectangle,

Credit HE-Arc CR.

Fig. 9: SEM image, BSE-mode, and elemental chemical distribution of the selected area from Fig. 8 (reversed picture, detail). Method of examination: SEM/EDS, Laboratory of Analytical Chemistry, Empa,

Passive

None

Complementary information

Nothing to report.

Fig. 4: Stratigraphic representation of the object in cross-section using the MiCorr application. This representation can be compared to Fig. 8, Credit HE-Arc CR.

Corrected stratigraphic representation: none.

Although not common at the beginning of the 20th, this Al-Cu-Sn-Zn-Si cast alloy was extensively used on the Dufaux IV plane. No corrosion layer has been found on the metal surface except adherent silica-rich particles and the thin oxidised skin typical of Al alloys. The presence of these materials might be explained by the regular maintenance of the metal using abrasive silicon carbide paper.

References on object and sample

References object

1. Rumo, L. (2008) Analyse et caractérisation des alliages constitutifs de l'avion Dufaux IV. Mémoire Filière conservation-restauration, Haute Ecole art appliqués, La Chaux-de-Fonds, 101-105.

References sample

2. Rumo, L. (2008) Analyse et caractérisation des alliages constitutifs de l'avion Dufaux IV. Mémoire Filière conservation-restauration, Haute école art appliqués, La Chaux-de-Fonds, 101-105.

References on analytic methods and interpretation